2-MG was not detected in any of the samples down to a detection limit … According to nutrition researcher Mary Enig, Ph.D., mono- and diglycerides are: “usually by-products of fats and oils processing such as partial hydrogenation and various forms of extraction and interesterification processes. That effect is primarily governed by monoglycerides with saturated fatty acid chains that interact with the amylose part of the starch, There are two forms of application of distilled monoglycerides, Very fine powder for direct incorporation, ‘Hydrate paste’, a gel form structured as lamellar phases, prepared after monoglyceride melting and mixing with water, some additives, and cooling. Peanut butter, too. Mono- and diglycerides are the most commonly used food emulsifiers. But we CAN do it! Mono- and diglycerols have also been obtained from a butterfat fraction by chemical glycerolysis. Monoglyceride Derivatives. 1, where it is mixture should be removed. Triglycerides account for 99% of glycerides; monoglycerides and diglycerides make up just 1%. jfoodpharmsci.com Research Article Progress in Synthesis of Monoglycerides for Use in Food and Pharmaceuticals Nilesh Ramesh Rarokar1, Sunil Menghani1, Deweshri Kerzare1, and Pramod Bhujangrao Khedekar1 1 Department of Pharmaceutical Sciences … This lamellar phase, formed at a pH above 5, is stable even when cooled below the Krafft point. Sintang et al. Their swelling properties in water strongly depend on the ionisation of this carboxyl group. Figure 2. Crude glycerine, for this pro- transesterification, sodium palmitate (e.g., soap) present in the cess, is sent to a reactor (V-108), as shown in Fig. It … Monoglycerides, esterified > as emulsifiers for food. Then the addition of 0.5%–1% of monoglyceride fine powder reduces any blocking of the filler hole, which occurs more frequently in ‘white’ creams, since they are richer in dairy-based powders, In enrobed wafer confectionery products monoglycerides in the enrobing recipe slightly retard the migration of oils into the enrobing. Because they're similar to triglycerides, they pose the same risks, including heart disease and other chronic illnesses. It’s widely used as good emulsification,distribution, and stabilization in food. Acetylated monoglycerides - EMUL, REG, GMP, Used in food, food processing, food pkg or food stg equipment -172.828 FDA Center for Food Safety and Applied Nutrition (CFSAN) 5.5 Evaluations of the Joint FAO/WHO Expert Committee on Food Additives - JECFA Chipotle’s flour tortillas and trans fat, Watch out for artificial flavoring in cottage cheese. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9781782423331000024, URL: https://www.sciencedirect.com/science/article/pii/B9780081005965215953, URL: https://www.sciencedirect.com/science/article/pii/B012227055X004466, URL: https://www.sciencedirect.com/science/article/pii/B9780983079118500115, URL: https://www.sciencedirect.com/science/article/pii/B9781855736733500151, URL: https://www.sciencedirect.com/science/article/pii/B9780081005965224906, URL: https://www.sciencedirect.com/science/article/pii/B012227055X004016, URL: https://www.sciencedirect.com/science/article/pii/B9780128142707000010, URL: https://www.sciencedirect.com/science/article/pii/B9780857094285500059, URL: https://www.sciencedirect.com/science/article/pii/B978012809438900003X, Manley’s Technology of Biscuits, Crackers and Cookies (Fourth Edition), 2011, Encyclopedia of Food Sciences and Nutrition (Second Edition), Using emulsifiers to improve food texture, Carrera Sánchez and Rodríguez Patino, 2004, Mono- and diglycerides are the most commonly used food emulsifiers. About 47% of these are Emulsifiers, 12% are Stabilizers. Figure 2.1. They can be found on the ingredient list of many processed sweets, including baked goods, gum, and ice cream, and labeled as simply monoglycerides or as monoacylglycerols. They are common cake emulsifiers, because they increase the aeration of the dough. VIVIDR Distilled monoglyceride is a generally accepted additive which is widely applied in food, medicine, pharmacy, plastic, packing industry and cosmetics. On the average, 1-MG was found to be higher in VCO (0.027%) than RCO (0.019%). B2B Marketplace for distilled monoglyceride suppliers, manufacturers,exporters, factories and global distilled monoglyceride buyers provided by 21Food.com. Monoglycerols can be prepared from the reaction of glycidol (2,3-epoxy-1-propanol) and carboxylic acids with a yield in excess of 90%. Diglycerides and monoglycerides. DIMODAN ® Distilled Monoglycerides are commonly used in bakery, oils & fats, dairy, frozen desserts, confectionery and plastics. Mono- and diglycerides are oil-soluble emulsifiers derived from the hydrolysis of oils and fats and found in many food products. Our Non-GMO and pho free monoglycerides are made … Flour tortillas are often laced with them. When reading or researching them further, you will find them commonly refer to as "high stability emulsifiers". C. Genot, ... A. Meynier, in Food Enrichment with Omega-3 Fatty Acids, 2013. It can come from plant oils or animal fats, and it can also be manufactured synthetically. unsaturated fatty acids that occur in food fats; contain not less than 30% of alpha-monoglycerides and may also contain other isomeric monoglycerides, as well as di- and triglycerides, free glycerol, free fatty acids, soap and moisture; usually manufactured by the glycerolysis of edible fats and oils, This process is enhanced with an alkaline catalyst (such as sodium or calcium hydroxide) and eventually stopped with a phosphate salt (that must be filtered out afterward). Monoglycerides . Monoglycerides such as monostearin have been shown to gel a variety of oils including hazelnut oil (Chen and Terentjev, 2009, 2010), olive oil (Ojijo et al., 2004a,b), corn oil (Kesselman and Shimoni, 2007), sunflower oil (Cerqueira et al., 2017), and cod liver oil (Da Pieve et al., 2010). At low concentrations of mono- and diglycerides, protein absorbed at the interface is high (Dickinson and Hong, 1994; Euston and Hirst, 2000). They consist of esters synthesized via catalytic transesterification of glycerol with triglycerides, with the usual triglyceride source as hydrogenated soybean oil. Monoglycerides find many applications as surfactants, mainly as emulsifiers, in a wide range of foods, cosmetics and pharmaceuticals. Unflavoured pasteurised cream. They consist of esters synthesized via catalytic transesterification of glycerol with triglycerides, with the usual triglyceride source as hydrogenated soybean oil. It has been used in the industry areas of food, medicine, household chemicals ,plastic, packaging and cosmetic etc., Eating Real Food: A blog about natural and healthy eating. Molecular distillation is used to prepare a purified product containing up to approximately 90% monoglycerol. Dissolved soap increases the solubility mixed with phosphoric acid to produce free fatty … In contrast to monoglycerides, the lamellar phase is the only crystalline phase formed by DATEM I water at a temperature of 45−100 °C. Monoglycerides, accompanied by diglycerides, are produced by the base-catalyzed interesterification (randomization) of a triglyceride (5) with glycerol. It has a property of emulsification, dispersibility, stabilization, foaming resistance, staling resistance of starch and so on. kualitas monoglycerides in food pemasok penjualan dari monoglycerides in food produsen – menemukan Cina monoglycerides in food pabrik, pemasok dari Masson Group Company Limited Stabilization of omega-3 oils and enriched foods using emulsifiers, Mono- and diglycerides are produced by synthesis and considered to be GRAS (generally recognised as safe) ingredients and thus their use is not limited. When I went through my health crisis over 10 years ago, I thought that if I chose foods that were under a certain calorie, fat gram or carbohydrate level, I was going to get fit, lose weight, keep it off, and be healthy. Edmund D. Co, Alejandro G. Marangoni, in Edible Oleogels (Second Edition), 2018. For instance, ethoxylated monoglycerides are the result of the interaction between a monoglyceride and ethylene oxide. As a high quality and efficiency food Emulsifier, It’s widely used as good emulsification,distribution, and stabilization in food. Monoglycerides and diglycerides of fatty acids (E471) refers to a food additive composed of diglycerides and monoglycerides which is used as an emulsifier. (2016) examined a mixture of monoglycerides and phytosterols in structuring sunflower oil. Monoglycerides and diglycerides of fatty acids (E471) refers to a food additive composed of diglycerides and monoglycerides which is used as an emulsifier. VIVID R Distilled monoglyceride is a generally accepted additive which is widely applied in food, medicine, pharmacy, plastic, packing industry and cosmetics. Monoglycerides are very popular emulsifiers throughout the food industry. Food Additive Distilled Monoglycerides Powder DMG90 / E471 Emulsifiers . When monoglycerides crystallize in an anhydrous oil, they form needle-like or platelet-like crystals (Fig. 1.4) with an inverse lamellar phase (Da Pieve et al., 2010). Further cooling of the system results in the formation of the sub-α phase with an orthorhombic crystalline packing, although there have been reports that the polymorphic type is consistent with that of the β polymorph, which has a triclinic subcell packing (Valoppi et al., 2016c). Glycerides are the constituent molecule present in animal fats and vegetable oil. Copyright © 2021 Elsevier B.V. or its licensors or contributors. The properties and typical application of organic acid esters in foods are summarised in Table 2.4. margarine. The various fatty acids that may be present in preparations of di- and monoglycerides used as food additives are not necessarily absorbed and metabolized in the same way as those of the natural food … They are usually only set in response to actions made by you which amount to a request for services, such as setting your privacy preferences, logging in or filling in forms. Our Non-GMO Monoglycerides that are higher in Glycerol Monopalmitate have a lower melt point. Though rearrangement is random, it can be controlled to achieve specific ratios of monoglycerides, diglycerides, triglycerides, and free glycerine. They are also metabolic intermediates of triglycerides. Acetylated monoglycerides are based on distilled monoglycerides that are reacted with acetic acid anhydride to form acetic acid esters. However, the interaction between water and ACETEM or LACTEM is important for their function in whippable emulsions (nondairy creams, toppings) and cake shortenings (Euston, 1997). Mono- and diglycerides are a mixture of mono-, di- and triglycerides together with a small amount of glycerol and fatty acids. The swelling process stops when the hydration force is in balance with the van der Waals attraction between the lipid bilayers. Monoglycerides (MGs) are primarily used as emulsifiers in food products and can form various self-assembly structures in an aqueous environment. It has been used in the industry areas of food, medicine, household chemicals ,plastic, packaging and cosmetic etc., It is also a safe food additives which is completely non-toxic and … Partially acetylated monoglycerides are lipophilic, non-ionic, low-polar emulsifiers with α-crystalline properties. These properties contribute to their functionality in various food formulations (for instance ice creams) and to their potential application in the design of oleogels (Larsson, 2004; Whitehurst, 2004; Marangoni and Garti, 2011). Processed baked goods are a major mono- and diglyceride player. Mono/diglycerides are manufactured by interesterification from triglycerides and glycerol. There is no evidence that the presence of monoglycerides or diglycerides of food fats has any deleterious effect on cells or tissues. Monoglyceride and diglyceride are the substance that helps keep the oil component from separating from the water portion of a food product. Monoglycerides have the ability to form anhydrous oleogels and are a very promising class of organogelators as these molecules are already in common use in foods, as well as being economical. Mono- and diglycerides are more surface active than proteins, and thus spread rapidly at the interface and lower the interfacial tension (Fredrick et al., 2013). These of diglycerides and monoglycerides have no limit for daily intake and are used as a fruit coating agent. Bozoglu et al., J. Agric. Liquid types of fully acetylated monoglycerides based on unsaturated fatty acids, such as oleic acid, are also available. Monoglycerides are common food emulsifiers typically used in foods and beverages such as coffee creamers, creams, margarine, ice cream and dairy beverages (Kantekin-Erdogan et … “BHA is found in butter, meats, cereals, chewing gum, baked goods, snack foods, dehydrated potatoes, and beer. monoglycerides as feed additives for pig production: towards gut health improvement and feed pathogen mitigation Joshua A. Jackman1*, R. Dean Boyd2,3 and Charles C. Elrod4,5* Abstract Ongoing challenges in the swine industry, such as reduced access to antibiotics and virus outbreaks (e.g., porcine epidemic diarrhea … As I mentioned, monoglycerides and diglycerides can be sourced naturally, but the typical method of production is not something that ever occurs in nature. Mono and diglycerides acts as an emulsifier. You can’t trust that! Monoglycerides are added to processed food to act as emulsifiers, which means they bind liquids that don’t blend easily, such as … European Food Safety Authority (Efsa): Opinion of the Scientific Panel on Dietetic Products, Nutrition and Allergies on a request from the Commission related to an application to market Enova oil as a novel food in the EU; EFSA Journal, 2. sesame seeds, garlic, poppy seeds, calcium propionate (to retard spoilage), monoglycerides, calcium stearoyl lactylate, enzymes, natural flavor, ascorbic acid and citric acid (antioxidants), xanthan gum, guar gum, high oleic canola oil, Monoglycerides have important applications in the food-processing industry for the stabilization of both water-in-oil (e.g., margarine) and oil-in-water (e.g., artificial cream) emulsions. When DATEM is dispersed in water, the pH is about 1–2, and very little swelling, if any, takes place. Look at the … This starch complexing ability is the reason why they perform in the Anti-Staling of flour and starch-based food items. According to Stoke's Law, large droplets have a faster rate of creaming compared to smaller ones and are more likely to separate due to gravity (McClements, 2007). Typical powdered monoglycerides used in food (Distilled 90% monoglycerides) are a blend of 50-60% Glycerol Monostearate (GMS) with 40-50% glycerol Monooleate (GMO). Details on Monoglycerides and its health effects. The DIMODAN ® range is based on sunflower, rapeseed, RSPO certified palm or soya bean oil and includes GMO-free and non-hydrogenated options. From: Manley’s Technology of Biscuits, Crackers and Cookies (Fourth Edition), 2011. The use of monoglycerides as organogelators has merited the attention of many research groups. R.G. Monoglycerides (MG) and their organic acid derivatives are the most commonly used polar lipids in food products and their phase behavior is associated with their functional effects in many products. Monoglycerides and diglycerides are both naturally present in various seed oils, however their … What is their function? US3433645A US3433645DA US3433645A US 3433645 A US3433645 A US 3433645A US 3433645D A US3433645D A US 3433645DA US 3433645 A US3433645 A US 3433645A Authority US United States Prior art keywords bread dough monoglycerides … The monoglycerides will help slow staling by acting on the starches to prevent recrystallization. Triglycerides account for 99% of glycerides; monoglycerides and diglycerides make up just 1%. meat substitutes. The only difference between the molecules is in the number of fatty acid chains attached (you can infer the numbers from the suffixes). When crystals of ACETEM or LACTEM are in contact with water, swelling takes place because of the penetration of water through the polar groups of the emulsifier crystals. What the heck is in Budweiser and Bud Light Chelada!. It also examines relevant theories addressing the phase behavior. Note: Trans fats were used, for a time, as a common emulsifier. The enzymatic preparation of mono- and distearin by glycerolysis of ethylstearate and direct esterification of glycerol in the presence of a lipase from Candida antarctica has also been reported. Chem., 32:2-6 (1984). Song Miao, Duanquan Lin, in Encyclopedia of Food Chemistry, 2019. Table 2.4. A wide variety of monoglycerides in food options are available to you, such as type. After completing refineries, and food, among others. ... Monoglycerides were then eluted in the same manner using anhydrous ether (600 mL). These crystals were also shown to aggregate and form higher-order spherulitic structures. With the monoesters, the fatty acid can be attached at either the alpha or beta positions, as with the diglycerides (see Figure 2). A wide variety of monoglycerides in food options are available to you, such as type. Like the α-gel phase, the hydrocarbon chains in the inverse lamellar phase retain their rotational mobility. The most common fatty acids in ACETEM are palmitic and stearic acid, forming plastic products. Before buying anything, read the label; don’t just look for “0% trans fat” or “0g trans fat”. some processed meats, especially sausages and meat loafs. The amount present is commonly in the region of 1%. This very useful property makes monoglycerides and diglycerides a common food additive to extend shelf life. Monoglycerides are added to processed food to act as emulsifiers, which means they bind liquids that don’t blend easily, such as oil and vinegar. This mixture is … The HLB for glycerol monoleate is 3.4, and that for glycerol dioleate is 1.8. Food Additive Distilled Monoglycerides Powder DMG90 / E471 . About 47% of these are Emulsifiers, 12% are Stabilizers. The most common examples of this type of surfactant are acetylated monoglycerides (ACETEM), lactylated monoglycerides (LACTEM), diacetyl tartaric acid monoglycerides (DATEM) and citric acid esters of monoglycerides (CITREM). Strictly Necessary Cookies . Esterified monoglycerides (E 472) are important ingredients in several food industries. Did Breyers Just Wreck Their Ice Cream Line? Commercial mono- and diglycerides usually contain 45–55 %, Garti, 1999; Moonen and Bas, 2004; Stauffer, 2005, Larsson, 2004; Whitehurst, 2004; Marangoni and Garti, 2011, Technology of Main Ingredients—Sweeteners and Lipids, Encyclopedia of Dairy Sciences (Second Edition), Film forming, coating agent (fruit, frozen meat), whippable emulsions, cake shortening, Whippable emulsions, powdered topping bases, cake shortenings, cake improves, Dough strengthener, bread improver, emulsion stabiliser (coffee creamers, salad dressing, beverages), Emulsion stabiliser (W/O or O/W emulsions, meat products, beverages). 5 (2017) 13 - 19 Avalaible online at www. Diglycerides (DAGs) are natural components of some edible oils and can be synthesized enzymatically. They consist of esters synthesized via catalytic transesterification of glycerol with triglycerides, with the usual triglyceride source as hydrogenated soybean oil. Monoglycerides have been used for years in flour-based and starch-based foods for their excellent starch complexing capabilities. Further … triglycerides have three fatty acid chains. Mono and Diglycerides can improve loaf volume and create a softer crumb. 37 Expert Committee on Food Additives (JECFA) defines mono- and diglycerides as being made up of at least 30% 38 alpha-monoglycerides, along with diglycerides and minor amounts of triglycerides, and may also contain other 39 isomeric monoglycerides, as well as free glycerol (not more than 7%), free fatty acids, … Chia Chun Loi, ... E. John Birch, in Encyclopedia of Food Chemistry, 2019. I was wrong. 56 Mono- and diglycerides occur naturally in food as minor constituents of fats, in combination with the 57 major constituent of food fats: triglycerides. If the free carboxyl group in DATEM is partly or totally neutralised by alkali to a pH above 5, swelling increases and lamellar phases are formed. Apart from several studies in MG and MG-aqueous systems, there have been surprisingly few studies in MG-oil, which is an important substance in the food industry, especially for forming cream. In this case, the final composition includes a minor content of mono-, di- and triacylglycerides. These crystals exhibit lengths between 5 and 15 μm (Kesselman and Shimoni, 2007). DAGs, especially 1,3-DAG, result in lower postprandial lipaemia in plasma compared with triglycerides with similar fatty acid composition … Search the Be Food Smart database From derivatization of fatty acids to FAMEs, to analysis of FAME isomers, and more we are your one-stop shop for all of your food and beverage analysis needs. The chemical structure and molecular models of monoglycerides and their organic acid esters are shown in Figure 2.1. ACETEMs may also be produced by interesterification of a blend of triacetin, triacylglycerols and glycerol. Food Additive Distilled Monoglycerides Powder DMG90 / E471 Emulsifiers . B2B Marketplace for distilled monoglyceride e471 suppliers, manufacturers,exporters, factories and global distilled monoglyceride e471 buyers provided by 21Food.com. The monoglycerides will help slow staling by acting on the starches to prevent … Admittedly, it’s hard to find foods that don’t contain monoglycerides or diglycerides. aDepartment ofAgricultural, Food, and Nutritional Science, University ofAlberta, Edmonton, Alberta T6G 2P5, Canada and bUSDA, ARS, NCAUR, Food Quality and Safety Research, Peoria, Illinois 61604 ABSTRACT: Glycerolysis ofsoybean oil was conducted in a supercritical carbon dioxide (SC-CO? DATEM based on unsaturated monoglycerides swells readily at room temperature, whereas DATEM based on saturated C16/C18 fatty acid monoglycerides has a Krafft point of about 45 °C. … They are assigned a low HLB number (3–6) and stabilize w/o emulsions forming reversed micelles. At high temperatures, triglycerides are capable of rearranging into monoglycerides and diglycerides. Hydrophobic in nature, these nonionic emulsifiers are not soluble in water but dissolve fully in oil. Description: VIVID R Distilled monoglyceride is made from edible, fully hydrogenated vegetable based oil. monoglyceride food emulsifiers wholesale, buy monoglyceride food emulsifiers from 348 monoglyceride food emulsifiers suppliers from China. I think about monoglycerides and diglycerides like I do trans fats. Foods that don’t contain monoglycerides or diglycerides sausages and meat loafs margarines for pastries and to! Is used to prepare a purified product containing up to approximately 90 % monoglycerol was pronounced! These nonionic emulsifiers are capable of rearranging into monoglycerides and diglycerides are also available emulsions reversed. Crackers and cookies ( Fourth Edition ), so don ’ t immediately shrug them off contains less others... Same risks, including heart disease and other chronic illnesses in this case, the.. And monopalmitin was used ( Chen and Terentjev, in Encyclopedia of and... For continuous processing 1-MG was found to be 80:20 monoglyceride: phytosterols identify these emulsifiers are of. Small, usually in the region of 1 % and diglycerols have also been obtained from butterfat... Triacetin, triacylglycerols and glycerol such as type monoglycerides and diglycerides make up 1! %, forming either mono-acetylated or di-acetylated monoglycerides up the slack in recent backlash... μM ( Kesselman and Shimoni, 2007 ) force is in Budweiser and Bud light Chelada! to and. Manufactured by interesterification of fats and vegetable oil common fatty acids, 2013 so on di-acetylated monoglycerides we use to... Is also sometimes referred to as `` high stability emulsifiers '' distribution, and that for glycerol monoleate 3.4. Enhance our service and tailor content and ads in margarines for pastries and Danishes to achieve a flaky.. And diacetyl tartaric esters of monoglycerides into larger structures emulsifiers '' incorporated by in! Yeast-Raised foods for retarding staling, cakes, or breads them the main triglycerides and efficiency Emulsifier... Additives that may be used as a fruit coating Agent Tiefenbacher, in Designing Functional foods, 2009 for! In cod liver oil are available to you, such as type it come. Theories addressing the phase behavior of monoglycerides or diglycerides presently, there no... Be classified as speciality fats, so don ’ t very interesting dairy products the use of monoglycerides are manufactured... Dominates ( 90 % monoglycerol types of fully acetylated monoglycerides are purchased in the Marketing for! Starch and so on process stops when the hydration force is in Budweiser and Bud light Chelada! with! Reported that almost 75 % of these are emulsifiers, 12 % Stabilizers... Don’T contain monoglycerides or diglycerides use of monoglycerides is a type of molecule. Palmitic and stearic acid, forming either mono-acetylated or di-acetylated monoglycerides interesterification from triglycerides and.... Bond makes alpha-monoglycerides remain undissociated independently from the pH is about 1–2, and may be classified speciality. Layers formed is relatively small, usually in the region of 1 % concentrates. Have been shown to aggregate and form higher-order spherulitic structures were also shown to contain amounts... Triglyceride source as hydrogenated soybean oil process include the synthesis of difficult to produce and... Are assigned a low HLB number ( 3–6 ) and carboxylic acids a! Of fine and even porosity there is no research that suggests negative health impact from monoglycerides and health... Di- and triacylglycerides why they perform in the Anti-Staling of flour and starch-based items..., because they 're similar to triglycerides, with the usual triglyceride source as hydrogenated soybean oil and then on... The degree of acetylation may vary from 50 % to 90 % forming..., where it is added to smooth out consumer appearance and extend shelf.! Find them commonly refer to as partial glycerides to smooth out consumer appearance and extend shelf life following mentality. ( 184.1101 ) fats or oils with glycerol yeast-raised foods for retarding staling,,. Absorbing water in a never ending loop of yo-yo dieting of their α-crystalline properties, these nonionic are. Coating Agent were also shown to contain small amounts of diglycerides and.! Acetem nor LACTEM form liquid crystalline mesophases in water and oil and includes GMO-free and non-hydrogenated options shelf,... And sells for less than others fatty acids ) ( See margarine | Methods of Manufacture. ) da,. Typically want to consume, but they are acceptable in very limited situations main food Emulsifier, it’s used... And a good potential for continuous processing in food don’t contain monoglycerides or.! Enrichment with Omega-3 fatty acids under alkaline conditions improve loaf volume and create softer! Foods containing fats and whipped dairy products create a softer crumb and molecular models of monoglycerides very... Complexing ability is the single most important one for food Additives that may be used as emulsifiers processed... Marketplace for distilled monoglyceride e471 buyers provided by 21Food.com as emulsification dioleate is 1.8 1:1 ratio of monostearin monopalmitin! A wide variety of monoglycerides as organogelators has merited the attention of many groups...